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Why in the News?

This newscard is an excerpt from the original article published in ‘The Hindu’.

About Soap:

  • Composition: Soap is sodium (Na) or potassium (K) salt of fatty acids derived from vegetable oils or animal fats.
  • Formula: Solid soaps are RCOONa, liquid soaps are RCOOK.
  • Function: Cleansing agent due to dual hydrophilic (water-attracting) and hydrophobic (oil-attracting) nature.
  • History: Used since 2800 BC in Mesopotamia and ancient India (soap nuts, bark, flowers). Became mass-produced during the Industrial Revolution, initially a luxury.

Soap-Making Process

  • Raw Materials: Oils such as coconut, olive, palm, sunflower provide triglycerides.
  • Hydrolysis: Oils hydrolysed with hot water under pressure → fatty acids + glycerin.
  • Saponification: Fatty acids react with sodium hydroxide (NaOH) → soap (RCOONa) + water.
  • Processing: Soap dried into noodles, blended with perfumes, colours, fillers, additives.
  • Shaping: Extruded, cut, and stamped into bars.
  • Quality: Total Fatty Matter (TFM) indicates quality; higher TFM = better cleansing.
  • Production Scale: Modern automated lines make 600–700 soaps per minute.

Ecological Impact of Soap

  • Biodegradability: Traditional soaps are biodegradable and safer for the environment.
  • Detergents: Synthetic alternatives developed during World War I oil shortages; more efficient but harmful.
  • Pollution: Surfactants and phosphates in detergents cause nutrient pollution and persist in ecosystems.
[UPSC 2002] Consider the following statements:

Assertion (A) Synthetic detergents can lather well in hard water.

Reason (R): Synthetic detergents form soluble calcium and magnesium salts with hard water.

Which one of the following is correct in respect of the above statements?

Options:

(a) Both A and R are individually true and R is the correct explanation of A *

(b) Both A and R are individually true but R is not a correct explanation of A

(c) A is true but R is false

(d) A is false but R is true

 

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